Generalized Kubo relations and conditions for anomalous diffusion: physical insights from a mathematical theorem.
نویسنده
چکیده
The paper describes an approach to anomalous diffusion within the framework of the generalized Langevin equation. Using a Tauberian theorem for Laplace transforms due to Hardy, Littlewood, and Karamata, generalized Kubo relations for the relevant transport coefficients are derived from the asymptotic form of the mean square displacement. In a second step conditions for anomalous diffusion are derived for the asymptotic forms of the velocity autocorrelation function and the associated memory function. Both spatially unconfined and confined diffusion processes are considered. The results are illustrated with semi-analytical examples.
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ورودعنوان ژورنال:
- The Journal of chemical physics
دوره 134 22 شماره
صفحات -
تاریخ انتشار 2011